The smoke infusion step works because cold liquid (0–2 °C post-shake) creates favorable partition coefficients for volatile phenols — guaiacol and syringol dissolve into the cocktail rather than staying airborne. Target 10–15 seconds under the cloche with apple or cherry wood chips; longer exposure pushes phenol concentration past the pleasurable threshold into harsh territory. Citric acid from the lime juice (pH 2.8–3.2) stabilizes orange-peel esters from the Cointreau and keeps the aromatic profile vivid. The combined agave and simple syrups (approx. 65 Brix blended) act as aromatic vehicles, carrying fat-soluble smoke phenols through the mid-palate and finish. Smoked sea salt on the rim suppresses bitterness receptors and amplifies both sweet and sour perception — rim only half the glass to allow the drinker to control sodium delivery sip by sip.